Matches include Manchester United's visit to Stamford Bridge, where fans can see how Chelsea's new manager gets on against the Red Devils following the departure of Jose Mourinho.
February's TV offer features 14 different teams in the top English division in what has become one of the most unpredictable seasons in history.
Sky Sports will also screen Man City's home match against Tottenham and Arsene Wenger's Arsenal who will visit Old Trafford.
The full February fixtures are listed below:
Sky Business managing director David Rey said: "Sky Sports is the only place to see all the stories of an increasingly unpredictable Premier League season, with drama every weekend to attract people into pubs and clubs to watch some huge fixtures. By March, there will still be 38 Premier League games to come on Sky Sports, which will be the place to see this thrilling season develop."
The live matches are part of 116 Premier League fixtures to be shown exclusively live on Sky Sports this season with analysis from Thierry Henry, Jamie Carragher, Jamie Redknapp and Graeme Souness.
Sky Sports is also providing 127 matches from Football League, 300 matches from La Liga, Capital One Cup, the climax of UEFA Euro 2016 qualification, action from Scotland in the SPFL and Scottish Cup, as well as MLS and Eredivisie.
February Premier League fixtures:
Bournemouth v Arsenal (Sunday 7 February, 1.30pm)
Chelsea v Man U (Sunday 7 February, 4pm)
Southampton v West Ham (Monday 8 February, 8pm)
Chelsea v Newcastle **(Saturday 13 February, 5.30pm)
Aston Villa v Liverpool (Sunday 14 February, 1.30pm)
Manchester City v Spurs (Sunday 14 February, 4pm)
West Brom v Crystal Palace (Saturday 27 February, 5.30pm)
Liverpool v Everton*** (Sunday 28 February, noon)
Newcastle v Man City**** (Sunday 28 February, noon)
Man U v Arsenal (Sunday 28 February, 2.05pm)
** This fixture will move to 5.30pm Saturday 6 February if either team is involved in an FA Cup replay
*** This match is subject to Capital One Cup Final participation. This match will be shown live on Sky Sports should it remain scheduled and Newcastle United v Manchester City has been postponed.
**** This fixture is subject to Manchester City's potential involvement in Capital One Cup Final